Nampoori, V P N; Kamalasanan, M N; Patel, M M(IOP, 1975)
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Abstract:
Indium monofluoride was excited in a high-frequency discharge and the C-X system was photographed at a reciprocal dispersion of 0.3 AA mm-1 using a plane-grating spectrograph. Rotational analyses of the 0,0 1,0 2,2 3,3 4,4 2,4 3,5 4,6 and 5,7 bands have been carried out and the following molecular constants have been evaluated. Be'=0.2670(+or-3) cm-1, Be"=0.2628(+or-4) cm-1, alpha e'=0.0050(+or-4) cm-1, alpha e"=0.0020(+or-1) cm-1, De'=3.65(+or-5)*10-7 cm-1, De"=2.5(+or-3)*10-7 cm-1, beta e'=0.5(+or-2)*10-7 cm-1, beta e"=0.2(+or-1)*10-7 cm-1, re'=1.9672(+or-3) AA, re"=1.9853(+or-2) AA. The re" value agrees with the microwave absorption value 1.9854 AA.
Lalitha, P R; Rao, V R; Nampoori, V P N(Current Science, 1980)
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Abstract:
Excitation and emission spectra of SrS : Mn : Ce phosphors have been studied in detail
at various Mn and Ce concentrations. In order to study the effect of external pressure on phosphors,
the samples were pretreated under various pressures. Four bands around 470 nm, 530 nm,
310 nm and 620 nm were observed, when the samples were excited with 265 nm radiation. The
effect of pressure is to reduce the fluorescence ability of the phosphors, and the luminescence
vanishes above O· 1 ton m-2 pressure. The fluorescence ability, however, can be regained on retiring
the sample. The emission mechanism has been attributed to two luminescentcenters in the forbidden
gap. An appreciable amount of photocurrent has also been observed for the sample.
Syamaprasad, U; Vallabhan, C P G(Institute of Physics, 1981)
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Abstract:
Four distinct peaks are observed at 140, -26, -132 and -140°C in the sigma x* against T-1 plot between 200 and - 196°C for (NH4)3H(SO4)2, corresponding to four different phase
transitions of which the one at -26°C is reported here for the first time. Data on doped
samples reveal the charge transport mechanism in the crystal.
Syamaprasad, U; Vallabhan, C P G(Elsevier, May , 1981)
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Abstract:
Anomalous variations of d.c. electrical conductivity with temperature are observed in ammonium sulphate single crystals, suggesting a possible phase transition at 150°C. Measurements of thermally stimulated current also support these results. The mechanism of electrical conduction is explained on the basis of studies made on doped and quenched crystals.
Measurements of dc conductivity and dielectric constant show that deuteration causes an upward shift of the high temperature phase transition point from 186.5 to 191°C and a downward shift of the low temperature transition point from 10 to -1.5°C in LiNH4SO4. Mechanisms of phase transitions and of electrical transport in the crystal are discussed.
Pillai, S M; Vallabhan, C P G(Solid State Communications, 1983)
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Abstract:
ZnS: Cu: Cl phosphor prepared under a vacuum firing process is found to
give blue electroluminescence with emission peak at 460 nm which remams
unaltered with the frequency of the excitation voltage. Addition of excess
chlorine in the phosphor gives blue, green and red emission at 460, 520
and 640 run. The intensity of the blue band decreases and It fmally
disappears as chlorine concentration is increased. A scheme involving
three energy levels attributed to Cu2+, Cu+ and Cl- centres in Zns
explains the experimental results completely.
Subhadra, V K; Syamaprasad, U; Vallabhan, C P G(American Institute of Physics, 1983)
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Abstract:
Results of axiswise measurements of the electrical conductivity (dc and ac) and dielectric constant of NH4H2PO4 confirm the occurrence of the recently suggested high‐temperature phase transition in this crystal (at 133 °C). The corresponding transition in ND4D2PO4 observed here for the first time takes place at 141.5 °C. The mechanism involved in these transitions and those associated with the electrical conduction and dielectric anomalies are explained on the basis of the motional effects of the ammonium ions in these crystals. Conductivity values for deuterated crystals give direct evidence for the predominance of protonic conduction throughout the entire range of temperatures studied (30–260 °C).
For the discrete-time quadratic map xt+1=4xt(1-xt) the evolution equation for a class of non-uniform initial densities is obtained. It is shown that in the t to infinity limit all of them approach the invariant density for the map.
Sreekumar, J; Nandakumaran, V M(Physics Letters, October 21, 1985)
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Abstract:
The phenomenon of two-soliton resonances of the Kadomtsev-Petviashvilli equation for the superfluid surface density fluctuation in He films is studied. The velocity of the resonant soliton is obtained.
Sudha Kartha, C; Ramachandran, T; Nampoori, V P N; Sathianandan, K(Solid State Communications, 1986)
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Abstract:
Variations in the decay times of the characteristic green emissions at 522.7, 551.3, 549.6, 547.6, 542.2, 540.2, 535.9 and 533.5nm from
CaF2 :H03+ with concentration are studied at RT and LNT. A pulsed N2
laser beam of power density 1.5 MW cm-2 is used for the excitation.
Temperature dependent concentration quenching of the decay times are
observed for all the emission bands. But an increase in the decay time due
to the reabsorption process is also observed for a few of the above bands.
Abdul Rasheed, T M; Nampoori, V P N; Sathianandan, K(Chemical Physics, 1986)
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Abstract:
The vibrational overtone spectra 0f the liquid phase 1,2-dichloroethane and 1,2-dibromoethane in the spectral regions of
CH stretching local mode overtones corresponding to delta v CH= = 2 to delta v CH=5 are reported. The observed spectral features are
assigned using the local mode model. LocaI mode frequencies WCH and diagonal local mode anharmonicities XCH are
obtained from an analysis of the spectra. The local-local combinations observed are interpreted on the basis of a coupled CH
oscillator model hamiltonian. Local-normal combinations show complex structures and their possible assignments are given.
Abdul Rasheed, T M; Moosad, K P B; Nampoori, V P N; Sathianandan, K(American Chemical Society, 1987)
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Abstract:
Vibrational overtone spectra of acetophenone and benzaldehyde in the visible and near-infrared regions are studied by the
dual beam thermal lens and the conventional near-infrared absorption techniques. The observed increase in the mechanical
frequency of the aryl CH bond from that of benzene is attributed to the decrease in the aryl CH bond length caused by
the electron-withdrawing property of the substituents. Overtone spectra also demonstrate that acetophenone contains two
types of methyl CH bonds arising from the anisotropic environments created by oxygen lone pair and carbonyl P electrons.
The local-mode parameters of the two types of CH bonds are compared with those of acetone and acetaldehyde. The possible
factors influencing the methyl CH bonds in acetophenone are discussed.
The role of acoustic plasmons in the recently discovered high Tc superconductors
is discussed. It is shown that the exchange of acoustic plasmons together with the
usual phonon exchange between electrons can give rise to a Tc - 100 K.
Lalaja, Varghese; Nampoori, V P N; Pratap, R(Current Science, October 20, 1987)
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Abstract:
A mathematical analysis of an electroencephalogram of a human Brain during an epileptic
seizure shows that the K2 entropy decreases as compared to a clinically normal brain while the
dimension of the attractor does not show significant deviation.
Reghunath, A T; Nampoori, V P N(Springer, November , 1987)
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Abstract:
Using laser transmission, the characteristics of hydrodynamic turbulence is studied following one of the recently developed technique in nonlinear dynamics. The existence of deterministic chaos in turbulence is proved by evaluating two invariants viz. dimension of attractor and Kolmogorov entropy. The behaviour of these invariants indicates that above a certain strength of turbulence the system tends to more ordered states.
Harikrishnan, K P; Nandakumaran, V M(Pramana, December , 1987)
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Abstract:
We have studied the bifurcation structure of the logistic map with a time dependant control parameter. By introducing a specific nonlinear variation for the parameter, we show that the bifurcation structure is modified qualitatively as well as quantitatively from the first bifurcation onwards. We have also computed the two Lyapunov exponents of the system and find that the modulated logistic map is less chaotic compared to the logistic map.
Harikrishnan, K P; Nandakumaran, V M(Elsevier, December 7, 1987)
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Abstract:
We study the period-doubling bifurcations to chaos in a logistic map with a nonlinearly modulated parameter and show that the bifurcation structure is modified significantly. Using the renormalisation method due to Derrida et al. we establish the universal behaviour of the system at the onset of chaos.
Pratap, R; Nampoori, V P N; Lalaja, Varghese(International Journal of Neuroscience, 1988)
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Abstract:
It is shown that the invariant integral, viz., the Kolmogorov second entropy, is eminently suited to characterize EEG quantitatively. The estimation obtained for a "clinically normal" brain is compared with a previous result obtained from the EEG of a person under epileptic seizure.
Ravisankar, M; Reghunath, A T; Sathianandan, K; Nampoori, V P N(Optical Society of America, September 15, 1988)
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Abstract:
The split-pulse laser method is used to reinvestigate the optical attenuation of distilled water in the region from 430 to 630 nm. The studies are then extended to ionic solutions of NaCl, MgCl2, and Na2SO4, these salts forming the major constituents of seawater. The effect of the concentration of these constituents on optical attenuation is investigated. Further, optical attenuation studies are carried out for the region from 430 to 630 nm for an aqueous solution prepared with all the major constituents in the same proportions as in natural seawater. These values are then compared with values obtained for natural seawater. The relative role of dissolved salts and suspended particles on optical attenuation in seawater is discussed. The lowest attenuation is observed at ~450 nm for all solutions and is found to coincide with that for distilled water.