Harilal, S S; Riju, C Issac; Bindhu, C V; Geetha K, Varier; Nampoori, V P N; Vallabhan, C P G(World Scientific Publishing Company, 1995)
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Abstract:
Pulsed photoacoustic measurements have been carried out in liquid CS2 using 532 nm radiation from a frequency doubled Nd:YAG laser. Variation of signal amplitude with laser fluence clearly indicates the role of multiphoton processes in the generation of photoacoustic effect. It is also shown that four photon induced dissociation and five photon induced ionization are likely processes in CS2 and 532 nm radiation.
Sathy, P; Reji, Philip; Nampoori, V P N; Vallabhan, C P G(Elsevier, January 1, 1990)
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Abstract:
Two-photon absorption in Rhodamine 6G using the second harmonic of a pulsed Q-switched Nd:YAG laser has been studied by photoacoustic technique. It is observed that there is a competition between one-photon and two-photon absorption processes. At lower concentration the two-photon process is predominant over the one-photon process.
Sasi Kumar, P R; Padmaja, G; Ravi Kumar, A V; Nampoori, V P N; Vallabhan, C P G(Springer, April , 1991)
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Abstract:
Observation of laser induced two-photon photoemission optogalvanic (TPPOG) effect from tungsten electrode in a discharge cell using 564 nm radiation obtained from a pulsed dye laser is described. The magnitude of the POG signal is studied as a function of laser energy under various discharge parameters. Competition between one-photon and two-photon processes has been observed when nitrogen gas is used in the discharge cell.
Reethamma, Thomas; Nampoori, V P N(Elsevier, December , 1988)
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Abstract:
Photoluminescence, thermoluminescence and phosphorescence studies of cerium and copper doped BaS phosphors are attempted. Cu+ centres in BaS lattice activate red emission while Ce3+ sensitize the blue emission. Results are explained on the basis of superposition theory involving monomolecular kinetics. In Randall and Wilkins model, the decay and TL studies are found to corelate each other.
The role of acoustic plasmons in the recently discovered high Tc superconductors
is discussed. It is shown that the exchange of acoustic plasmons together with the
usual phonon exchange between electrons can give rise to a Tc - 100 K.
Nibu, A George; Vallabhan, C P G; Nampoori, V P N; George, A K; Radhakrishnan, P(Society of Photo-Optical Instrumentation Engineers, 2001)
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Abstract:
We report the use of an open photoacoustic cell configuration
for the evaluation of thermal effusivity of liquid crystals. Initially, the
method is calibrated using water and glycerol as transparent liquid
samples, and the role of thermal conductivity of these liquids on the
photoacoustic signal amplitude is discussed. To demonstrate the application
of the present method for the evaluation of thermal effusivity of
liquid crystals, we have used certain multicomponent nematic liquid crystal
mixtures, namely BL001, BL002, BL032, and BL035. Each of these
liquid crystal mixtures contains four to nine components and are primarily
based on the cyanobiphenyl structure. The measured values of thermal
effusivity of BL001 and BL002 were found to be almost the same, but
differ from those of BL032 and BL035, which implies a difference in
composition of the latter two from the former two mixtures.
Kumar, G A; Thomas, J; George, N; Kumar, B A; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(Society of Glass Technology, 2000)
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Abstract:
Optical absorption studies of free base and rare earth incorporated phthalocyanine doped borate glass matrix are reported for the first lime. The absorption spectra recorded in the UV- VIS region show two well defined absorption bands of phthalocyanine (Pc) molecule, namely the Soret band (B) and the Q band. The Q band always shows its characteristic splitting in all the doped glass matrices and the intensities of these components are found to vary from one Pc to another. Some of the important optical parameters, namely optical absorption coefficient (a), molar extinction coefficient (ε), absorption cross section (σa), oscillator strength (f), electric dipole strength (q2), absorption half bandwidth (Δλ) of the principal optical transitions have also been evaluated. Moreover, the spectral dependence of refractive index (n) and thereby the optical dielectric constant (ε) on wavelength yielded values of carrier concentration to effective mass ratio (N/m*) of the phthalocyanine molecule in the present glassy systems. Optical band gap (Eg) and width of the band tail (Et) are computed and their variations among the prepared samples are also discussed.
Girijavallabhan, C P; Nampoori, V P N; Harilal, S S; Riju, C Issac; Bindhu, C V(Journal of Physics D : Applied Physics, January 24, 1997)
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Abstract:
Optical emission studies of C2 molecules in plasma obtained by Nd:YAG
laser ablation of graphite in a helium atmosphere are reported for irradiances in the
range (1–9:2/ x 1010 W cm−2. The characteristics of the spectral emission intensity
from the C2 (Swan band) species have been investigated as functions of the
distance from the target, ambient pressure and laser irradiance. Estimates of
vibrational temperatures of C2 species under various irradiance conditions are
made. Results of measurements performed under different ambient helium gas
pressures are also discussed.
Nampoori, V P N; Girijavallabhan, C P; Harilal, S S; Riju, C Issac; Bindhu, C V(Journal of Physics D : Applied Physics, January 24, 1997)
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Abstract:
Optical emission studies of C2 molecules in plasma obtained by Nd:YAG
laser ablation of graphite in a helium atmosphere are reported for irradiances in the
range (1–9:2/ x 1010 W cm−2. The characteristics of the spectral emission intensity
from the C2 (Swan band) species have been investigated as functions of the
distance from the target, ambient pressure and laser irradiance. Estimates of
vibrational temperatures of C2 species under various irradiance conditions are
made. Results of measurements performed under different ambient helium gas
pressures are also discussed.
Deepa, Jose; Shelly John, M; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(Elsevier, July 18, 1998)
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Abstract:
A novel fibre optic sensor for the in situ measurement of the rate of deposition of thin films has been developed. Evanescent wave in the uncladded portion of a multimode fibre is utilised for this sensor development. In the present paper we demonstrate how this sensor is useful for the monitoring of the deposition rate of polypyrrole thin films, deposited by an AC plasma polymerisation method. This technique is simple, accurate and highly sensitive compared with existing techniques.
Harilal, S S; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, 1999)
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Abstract:
Optical limiting and thermo-optic properties of C60 in toluene are studied using 532 nm, 9 ns pulses from a frequency-doubled Nd:YAG laser. Optical limiting studies in these fullerene molecules lead to the conclusion that reverse saturable absorption is the major mechanism for limiting properties in these molecules. Thermal lensing measurements are also performed in fullerene solutions. The quadratic dependence of thermal lens signal on incident energy confirms that enhanced optical absorption by the sample via excited triplet state absorption may play a leading role in the limiting property.
Aneeshkumar, B; Pramod, Gopinath; Vallabhan, C P G; Nampoori, V P N; Radhakrishnan, P(Optical Society of America, July , 2003)
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Abstract:
The nanosecond optical-limiting characteristics (at 532 nm) of some rare-earth metallo-phthalocyanines (Sm(Pc)2, Eu(Pc)2, and LaPc) doped in a copolymer matrix of poly(methyl methacrylate) and methyl-2-cyanoacrylate have been studied for the first time to our knowledge. The optical-limiting response is attributed to reverse saturable absorption due to excited-state absorption. The performance of LaPc in a copolymer host is studied at different linear transmissions. The laser damage thresholds of all the samples are also reported.
Kumar, G A; Thomas, J; Unnikrishnan, N V; Nampoori, V P N; Vallabhan, C P G(Elsevier, 2001)
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Abstract:
Optical absorption and emission spectral studies of various phthalocyanine molecules, viz., LaPc, NdPc, SmPc, EuPc, CuPc and ZnPc in a polymer matrix of cyano acrylate are reported for the first time. All the absorption spectra show an intense B band (Soret) in the UV region followed by a weaker Q band in the visible region. The positions of the Q and B bands are found to have dependence on the metallic substitution. Values of the important spectral parameters, viz., molar extinction coefficient (ϵ), oscillator strength (f), radiative transition rate and decay time of the excited singlet state are also presented and compared with other solid matrices. The recorded fluorescence spectrum shows two broad emission bands in the case of NdPc, whereas for ZnPc only a very weak band is observed. The absence of emission bands for the other metallated phthalocyanines is attributed to increased spin orbit interaction and intersystem crossing.
Kumar, G A; Vinoy, Thomas; Gin, Jose; Unnikrishnan, N V; Nampoori, V P N(Elsevier, 2002)
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Abstract:
Optical properties of free and substituted porphyrins (PP) doped borate glass matrix are reported for the first time. Absorption spectral measurements of H2TPP, CdTPP, MgTPP and ZnTPP doped borate glass matrix have been made in the 200–1100 nm region and the spectra obtained are analyzed to obtain the optical bandgap (Eg) and other important spectral parameters viz. oscillator strength (f), molar extinction coefficient (ε), electric dipole strength (q2), absorption cross-section (σa) and molecular concentration (N). Intense fluorescence was observed in the region 668–685 nm for CdTPP, ZnTPP and MgTPP doped matrices, whereas no such fluorescence was observed in H2TPP doped matrix. Fluorescence intensity was observed to be almost similar in all the metallated porphyrine matrices. Fluorescence bandwidth (Δλ), decay time (τ), stimulated emission cross-section (σ) and optical gain (G) of the principal fluorescence transitions corresponding to the Q-band excitation were also evaluated and discussed.
Thomas, J; Kumar, G A; Unnikrishnan, N V; Nampoori, V P N; Vallabhan, C P G(Elsevier, 2000)
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Abstract:
Optical absorption and emission spectral studies of various phthalocyanine (Pc) molecules in PVA matrix have been reported for the first time. The recorded spectra are analyzed to get the important spectral parameters, such as optical absorption cross-section (σa), emission cross-section (σe), oscillator strength (f), fluorescence bandwidth (Δλ), emission wavelength (λ), radiative decay time (τ) and optical gain (G). Analysis shows that the emission cross-section and optical gain are maximum in the NdHPc2-doped PVA matrix. However, a comparison of the calculated emission parameters with that of borate glass matrix show that they are many times smaller in the present matrix.
Abdul Rasheed, T M; Nampoori, V P N; Sathianandan, K(Chemical Physics, 1986)
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Abstract:
The vibrational overtone spectra 0f the liquid phase 1,2-dichloroethane and 1,2-dibromoethane in the spectral regions of
CH stretching local mode overtones corresponding to delta v CH= = 2 to delta v CH=5 are reported. The observed spectral features are
assigned using the local mode model. LocaI mode frequencies WCH and diagonal local mode anharmonicities XCH are
obtained from an analysis of the spectra. The local-local combinations observed are interpreted on the basis of a coupled CH
oscillator model hamiltonian. Local-normal combinations show complex structures and their possible assignments are given.
Abdul Rasheed, T M; Moosad, K P B; Nampoori, V P N; Sathianandan, K(Springer, September , 1989)
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Abstract:
Vibrational overtone spectra of styrene (liquid) and polystyrene (solid), studied by the laser-induced thermal lens (for ΔV=6) and the conventional near infrared absorption (for ΔV=3–5) techniques, are reported. For polystyrene, the overtone energy-bond length correlation predicts that the aryl CH bonds are ∼0.0005 Å longer than that in benzene, while no such conclusions could be drawn on styrene. Thesp 3 CH overtones in polystyrene are observed on the low energy side of the aryl CH overtones.
Bindhu M, Krishna; Manu P, John; Nandakumaran, V M(Indian Academy of Sciences, December , 2008)
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Abstract:
The chaotic dynamics of directly modulated semiconductor lasers with delayed optoelectronic feedback is studied numerically. The effects of positive and negative delayed optoelectronic feedback in producing chaotic outputs from such lasers with nonlinear gain reduction in its optimum value range is investigated using bifurcation diagrams. The results are confirmed by calculating the Lyapunov exponents. A negative delayed optoelectronic feedback configuration is found to be more effective in inducing chaotic dynamics to such systems with nonlinear gain reduction factor in the practical value range.
Usha, Nair; Bindu M, Krishna; Namboothiri, V N N; Nampoori, V P N(Springer, 2010)
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Abstract:
Machine tool chatter is an unfavorable phenomenon during metal cutting, which results in heavy vibration of cutting tool. With increase in depth of cut, the cutting regime changes from chatter-free cutting to one with chatter. In this paper, we propose the use of permutation entropy (PE), a conceptually simple and computationally fast measurement to detect the onset of chatter from the time series using sound signal recorded with a unidirectional microphone. PE can efficiently distinguish the regular and complex nature of any signal and extract information about the dynamics of the process by indicating sudden change in its value. Under situations where the data sets are huge and there is no time for preprocessing and fine-tuning, PE can effectively detect dynamical changes of the system. This makes PE an ideal choice for online detection of chatter, which is not possible with other conventional nonlinear methods. In the present study, the variation of PE under two cutting conditions is analyzed. Abrupt variation in the value of PE with increase in depth of cut indicates the onset of chatter vibrations. The results are verified using frequency spectra of the signals and the nonlinear measure, normalized coarse-grained information rate (NCIR).
Ravi Kumar, A V; Padmaja, G; Nampoori, V P N; Vallabhan, C P G(Springer, November , 1989)
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Abstract:
Absorption spectra of formaldehyde molecule in the gas phase have been recorded using photoacoustic (PA) technique with pulsed dye laser at various power levels. The spectral profiles at higher power levels are found to be different from that obtained at lower laser powers. Two photon absorption (TPA) is found to be responsible for the photoacoustic signal at higher laser power while the absorption at lower laser power level is attributed to one photon absorption (OPA) process. Probable assignments for the different transitions are given in this paper.