Parvathi, R; Indic, P; Nampoori, V P N(Elsevier, February 11, 2002)
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Abstract:
Nonlinear time series analysis is employed to study the complex behaviour exhibited by a coupled pair of Rossler systems. Dimensional analysis with emphasis on the topological correlation dimension and the Kolmogorov entropy of the system is carried out in the coupling parameter space. The regime of phase synchronization is identified and the extent of synchronization between the systems constituting the coupled system is quantified by the phase synchronization index. The effect of noise on the coupling between the systems is also investigated. An exhaustive study of the topological, dynamical and synchronization properties of the nonlinear system under consideration in its characteristic parameter space is attempted.
Riju, C Issac; Vasudevan Pillai, K; Harilal, S S; Geetha K, Varier; Bindhu, C V; Pramod, Gopinath; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(Elsevier Science, 1998)
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Laser produced plasma from silver is generated using a Q-switched Nd:YAG laser. Optical emission spectroscopy is used
to carry out time of flight (TOF) analysis of atomic particles. An anomalous double peak profile in the TOF distribution is
observed at low pressure. A collection of slower species emerge at reduced pressure below 4 X lO-3 mbar and this species
has a greater velocity spread. At high pressure the plasma expansion follows the shockwave model with cylindrical
symmetry whereas at reduced pressure it shows unsteady adiabatic expansion (UAE). During UAE the species show a
parabolic increases in the expansion time with radial distance whereas during shock wave expansion the exponent is less
than one. The angular distribution of the ablated species in the plume is obtained from the measurement of optical density of
thin films deposited on to glass substrates kept perpendicular to the plume. There is a sharp variation in the film thickness
away from the film centre due to asymmetries in the plume.
Saratchandran, P P; Nandakumaran, V M; Ambika, G(Springer, November , 1996)
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By introducing a periodic perturbation in the control parameter of the logistic map we have investigated the period locking properties of the map. The map then gets locked onto the periodicity of the perturbation for a wide range of values of the parameter and hence can lead to a control of the chaotic regime. This parametrically perturbed map exhibits many other interesting features like the presence of bubble structures, repeated reappearance of periodic cycles beyond the chaotic regime, dependence of the escape parameter on the seed value and also on the initial phase of the perturbation etc.
Thomas, Kuruvilla; Nandakumaran, V M(Indian Academy of Sciences, March , 2000)
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The effect of coupling two chaotic Nd:YAG lasers with intracavity KTP crystal for frequency doubling is numerically studied for the case of the laser operating in three longitudinal modes. It is seen that the system goes from chaotic to periodic and then to steady state as the coupling constant is increased. The intensity time series and phase diagrams are drawn and the Lyapunov characteristic exponent is calculated to characterize the chaotic and periodic regions.
Manu P, John; Jijo, P U; Nandakumaran, V M(Indian Academy of Sciences, March , 2009)
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Abstract:
We study the effect of parameter fluctuations and the resultant multiplicative
noise on the synchronization of coupled chaotic systems. We introduce a new quantity,
the fluctuation rate Ф as the number of perturbations occurring to the parameter in unit
time. It is shown that ϕ is the most significant quantity that determines the quality of
synchronization. It is found that parameter fluctuations with high fluctuation rates do not
destroy synchronization, irrespective of the statistical features of the fluctuations. We also
present a quasi-analytic explanation to the relation between ϕ and the error in synchrony.
Sony, George; Ajai, Kumar; Singh, R K; Nampoori, V P N(Springer, 2010)
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Abstract:
A study has been carried out to understand the
influence of ambient gases on the dynamics of laser-blow-off
plumes of multi-layered LiF–C thin film. Plume images
at various time intervals ranging from 100 to 3000 ns have
been recorded using an intensified CCD camera. Enhancement
in the plume intensity and change in size and shape
occurs on introducing ambient gases and these changes are
highly dependent on the nature and composition of the ambient
gas used. Velocity of the plume was found to be
higher in helium ambient whereas intensity enhancement is
greater in argon environment. The plume shapes have maximum
size at 10−2 and 10−1 Torr of Ar and He pressures,
respectively. As the background pressure increases further
(>10−2 Torr: depending on the nature of gas), the plume
gets compressed/focused in the lateral direction. Internal
structure formation and turbulences are observed at higher
pressures (>10−1 Torr) in both ambient gases.
Litty, Irimpan; Ambika, D; Kumar, V; Nampoori, V P N; Radhakrishnan, P(American Institute of Physics, 2008)
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The annealing effect on the spectral and nonlinear optical NLO characteristics of ZnO thin films
deposited on quartz substrates by sol-gel process is investigated. As the annealing temperature
increases from 300–1050 °C, there is a decrease in the band gap, which indicates the changes of the
interface of ZnO. ZnO is reported to show two emission bands, an ultraviolet UV emission band
and another in the green region. The intensity of the UV peak remains the same while the intensity
of the visible peak increases with increase in annealing temperature. The role of oxygen in ZnO thin
films during the annealing process is important to the change in optical properties. The mechanism
of the luminescence suggests that UV luminescence of ZnO thin films is related to the transition
from conduction band edge to valence band, and green luminescence is caused by the transition
from deep donor level to valence band due to oxygen vacancies. The NLO response of these
samples is studied using nanosecond laser pulses at off-resonance wavelengths. The nonlinear
absorption coefficient increases from 2.9 ×10−6 to 1.0 ×10−4 m/W when the annealing temperature
is increased from 300 to 1050 °C, mainly due to the enhancement of interfacial state and exciton
oscillator strength. The third order optical susceptibility x(3) increases with increase in annealing
temperature (T) within the range of our investigations. In the weak confinement regime, T2.4
dependence of x(3) is obtained for ZnO thin films. The role of annealing temperature on the optical
limiting response is also studied.
James, Joseph; Ananthakrishnan, T R; Nampoori, V P N; Rudra Warier, M K; Karanjikar, N P; Kamat, M J(World Scientific Publishing Company, 1995)
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Abstract:
The effect of Ce3+ on the fluorescence emission from CaS:Ce3+ phosphor is studied using X-ray excitation. Apart from the emission in the visible region, the phosphor also shows fluorescence emission in the ultraviolet region. Variation in wavelengths and intensities of these emissions due to change in dopant concentration is also analysed.
Pillai, S M; Vallabhan, C P G(Solid State Communications, 1983)
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ZnS: Cu: Cl phosphor prepared under a vacuum firing process is found to
give blue electroluminescence with emission peak at 460 nm which remams
unaltered with the frequency of the excitation voltage. Addition of excess
chlorine in the phosphor gives blue, green and red emission at 460, 520
and 640 run. The intensity of the blue band decreases and It fmally
disappears as chlorine concentration is increased. A scheme involving
three energy levels attributed to Cu2+, Cu+ and Cl- centres in Zns
explains the experimental results completely.
Measurements of dc conductivity and dielectric constant show that deuteration causes an upward shift of the high temperature phase transition point from 186.5 to 191°C and a downward shift of the low temperature transition point from 10 to -1.5°C in LiNH4SO4. Mechanisms of phase transitions and of electrical transport in the crystal are discussed.
Ravisankar, M; Reghunath, A T; Sathianandan, K; Nampoori, V P N(Optical Society of America, September 15, 1988)
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Abstract:
The split-pulse laser method is used to reinvestigate the optical attenuation of distilled water in the region from 430 to 630 nm. The studies are then extended to ionic solutions of NaCl, MgCl2, and Na2SO4, these salts forming the major constituents of seawater. The effect of the concentration of these constituents on optical attenuation is investigated. Further, optical attenuation studies are carried out for the region from 430 to 630 nm for an aqueous solution prepared with all the major constituents in the same proportions as in natural seawater. These values are then compared with values obtained for natural seawater. The relative role of dissolved salts and suspended particles on optical attenuation in seawater is discussed. The lowest attenuation is observed at ~450 nm for all solutions and is found to coincide with that for distilled water.
Litty, Irimpan; Deepthy, A; Bindu, Krishnan; Kukreja, L M; Nampoori, V P N; Radhakrishnan, P(Elsevier, 2008)
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In the present work, we report the third order nonlinear optical properties of ZnO thin films deposited using self assembly, sol gel process as well as pulsed laser ablation by z scan technique. ZnO thin films clearly exhibit a negative nonlinear index of refraction at 532 nm and the observed nonlinear refraction is attributed to two photon absorption followed by free carrier absorption. Although the absolute nonlinear values for these films are comparable, there is a change in the sign of the absorptive nonlinearity of the films. The films developed by dip coating and pulsed laser ablation exhibit reverse saturable absorption whereas the self assembled film exhibits saturable absorption. These different nonlinear characteristics in the self assembled films can be mainly attributed to the saturation of linear absorption of the ZnO defect states.
Santhi, A; Umadevi, M; Ramakrishnan, V; Radhakrishnan, P; Nampoori, V P N(Elsevier, 2004)
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Abstract:
Nano structured noble metals have very important applications in diverse fields as photovoltaics, catalysis, electronic and magnetic devices, etc. Here, we report the application of dual beam thermal lens technique for the determination of the effect of silver sol on the absolute fluorescence quantum yield (FQY) of the laser dye rhodamine 6G. A 532 nm radiation from a diode pumped solid state laser was used as the excitation source. It has been observed that the presence of silver sol decreases the fluorescence quantum efficiency. This is expected to have a very important consequence in enhancing Raman scattering which is an important spectrochemical tool that provides information on molecular structures. We have also observed that the presence of silver sol can enhance the thermal lens signal which makes the detection of the signal easier at any concentration.
Sajan, D George; Augustine, S; Mathai, E; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(WILEY-VCH Verlag GmbH&Co, 2003)
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Abstract:
An open cell configuration has been employed for the photoacoustic measurement of the thermal diffusivity of undoped Bi2Se3 crystals and Bi2Se3 crystals doped with various concentrations of Te. The amplitude of the photoacoustic signal obtained under heat transmission configuration as a function of chopping frequency is used to evaluate the numerical value of thermal diffusivity, α. Doped samples show a substantial reduction in the value of α compared to undoped samples. The variations in the thermal diffusivity of the doped samples are explained in terms of the phonon assisted heat transfer mechanism. It is seen that α is very sensitive to structural variations arising from doping. The experimentally observed results are correlated with X-ray diffraction studies.
Syamaprasad, U; Vallabhan, C P G(Elsevier, May , 1981)
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Anomalous variations of d.c. electrical conductivity with temperature are observed in ammonium sulphate single crystals, suggesting a possible phase transition at 150°C. Measurements of thermally stimulated current also support these results. The mechanism of electrical conduction is explained on the basis of studies made on doped and quenched crystals.
Navil Kumar, R; Vallabhan, C P G(IOP Publishing, 1989)
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DC and AC electrical conductivity measurements in single crystals of diammonium hydrogen phosphate along the c axis show anomalous variations at 174, 246 and 416 K. The low-frequency dielectric constant also exhibits peaks exactly at these temperatures with a thermal hysteresis of 13 degrees C for the peak at 416 K. These specific features of the electrical properties are in agreement with earlier NMR second-moment data and can be identified with three distinct phase transitions that occur in the crystal. The electrical conductivity values have been found to increase linearly with impurity concentration in specimens doped with a specific amount of SO42- ions. The mechanisms of the phase transition and of the electrical conduction process are discussed in detail.
Santhakumari, N C; Vallabhan, C P G(Elsevier, May , 1992)
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D.C. and a.c. electrical conductivities, dielectric constant and dielectric loss factor in single crystals of ethylenediammonium sulphate, (H3NCH2CH2NH3)(SO4), have been measured axiswise as a function of temperature. Anomalous variations in all the above properties at 480 K indicate the occurrence of a phase transition in the above material at this temperature. The existence of such a phase transition is also confirmed by DSC measurements. Electrical conductivity results are analysed and the activation energies of conduction at different temperature regions have been evaluated from the logσ vs 103T−1 plot. Possible mechanisms for the electrical conduction process are discussed, the available results being in favour of a proton transport model.
Santhakumari, N C; Vallabhan, C P G(Elsevier, April , 1991)
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Abstract:
dc and ac electrical conductivities, dielectric constant and dielectric loss factor in single crystals of ethylenediammonium dinitrate (EDN) have been measured axiswise as a function of temperature. All the above properties exhibit anomalous variations at 404 K thereby confirming the occurence of a phase transition in EDN at this temperature. Electrical conductivity parameters have been evaluated and possible conduction mechanisms are discussed. The role of protons in electrical trasport phenomenon is established by chemical analysis.
Harilal, S S; Bindhu, C V; Issac, Riju C; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, September 1, 1997)
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Abstract:
Plasma generated by fundamental radiation from a Nd:YAG laser focused onto a graphite target is studied spectroscopically. Measured line profiles of several ionic species were used to infer electron temperature and density at several sections located in front of the target surface. Line intensities of successive ionization states of carbon were used for electron temperature calculations. Stark broadened profiles of singly ionized species have been utilized for electron density measurements. Electron density as well as electron temperature were studied as functions of laser irradiance and time elapsed after the incidence of laser pulse. The validity of the assumption of local thermodynamic equilibrium is discussed in light of the results obtained.
Geetha K, Varier; Harilal, S S; Bindhu, C V; Riju, C Issac; Nampoori, V P N; Vallabhan, C P G(December 3, 2011)
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Irradiation of a Polymethyl methacrylate target using a pulsed Nd-YAG laser causes plasma formation in the vicinity of the target. The refractive index gradient due to the presence of the plasma is probed using phase-shift detection technique. The phase-shift technique is a simple but sensitive technique for the determination of laser ablation threshold of solids. The number density of laser generated plasma above the ablation threshold from Polymethyl methacrylate is calculated as a function of laser fluence. The number density varies from 2×1016 cm-3 to 2×1017 cm-3 in the fluence interval 2.8-13 J · cm-2.