Sugunan, S(Indian Journal of Chemistry, September , 1984)
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Abstract:
The Setschenow parameters of solubility in salt solutions and the
thermodynamic parameters (25·C) of transfer from aqueous
solution to aqueous salt solutions for 2-nitrobenzoic acid and 3-nitrobenzoic
acid have been reported. The data have been
rationalized on the basis of the localized hydrolysis model and the
structure breaking action of ions of the electrolytes.
Sugunan, S; Thomas, B(American Chemical Society, 1995)
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Abstract:
The Setschenow parameter and thermodynamic parameters of transfer of 2- and 4-aminobenzoic acids
from water to salt solutions have been reported. The results are discussed in terms of the structure- breaking
effects of the ions of the salts, the localized hydrolysis model, and the internal pressure theory.