| dc.contributor.author |
Sugunan, S |
|
| dc.contributor.author |
Nishamol, K |
|
| dc.date.accessioned |
2011-08-23T11:47:02Z |
|
| dc.date.available |
2011-08-23T11:47:02Z |
|
| dc.date.issued |
2002-05 |
|
| dc.identifier.other |
Indian Journal of Chemistry Vol. 41A, May 2002, pp. 928-933 |
|
| dc.identifier.uri |
http://dyuthi.cusat.ac.in/purl/2210 |
|
| dc.description.abstract |
The liquid-phase Friedel-Crafts acylation of toluene using benzoyl chloride as benzoylating agent has heen carried out over Nix, Mn(l-x)Fe2 O4 (x=O, 0.2, 0.4, 0.6, 0.8 and 1.0) type systems under different reaction conditions. It is observed that the systems with high 'x' values are effective for the conversion of BOC and the selective formation of 4-MBP. Selectivity for 4-MBP over MnFe2O4 is more than 90% under the optimized reaction conditions. Sites of moderate acidity is effective in calalyzing the benzoylation reaction. |
en_US |
| dc.description.sponsorship |
Cochin University of Science and Technology |
en_US |
| dc.language.iso |
en |
en_US |
| dc.publisher |
Indian Journal of Chemistry |
en_US |
| dc.subject |
Liquid-phase Friedel-Crafts acylation |
en_US |
| dc.subject |
Chemistry |
en_US |
| dc.subject |
catalysts |
en_US |
| dc.title |
Liquid-phase Friedel-Crafts acylation using NixMn(l-x)Fe2O4 spinel catalysts |
en_US |
| dc.type |
Working Paper |
en_US |
| dc.contributor.faculty |
Science |
en_US |