Veena Gopalan, E; Dr.Anantharaman, M R(Cochin University of Science & Technology, June , 2009)
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Abstract:
This thesis lays importance in the preparation and characterization of a
few selected representatives of the ferrite family in the nanoregime. The candidates being manganese zinc ferrite and cobalt ferrite prepared by coprecipitation
and sol-gel combustion techniques respectively. The thesis not only
stresses importance on the preparation techniques and optimization of the reaction
conditions, but emphasizes in investigating the various properties namely
structural, magnetic and electrical. Passivated nickel nanocomposites are
synthesized using polystyrene beads and adopting a novel route of ion exchange
reduction. The structural and magnetic properties of these magnetic
nanocomposites are correlated. The magnetocaloric effect (MCE) exhibited by
these materials are also investigated with a view to finding out the potential of
these materials as magnetic refrigerants. Calculations using numerical methods
are employed to evaluate the entropy change on selected samples.
Description:
Department of Physics,
Cochin University of Science & Technology
Santhosh, Shenoy D; Anantharaman, M R(COCHIN UNIVERSITY OF SCIENCE AND TECHNOLOGY, July , 2004)
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Abstract:
The present work is an attempt to understand the characteristics of high energy ball milling on the structural, electrical and magnetic properties of some normal spinets in the ultra fine regime, Magnetism and magnetic materials have been a fascinating subject for the mankind ever since the discovery of lodestone. Since then, man has been applying this principle of magnetism to build devices for various applications. Magnetism can be classified broadly into five categories. They are diamagnetic, paramagnetic, ferromagnetic antiferromagnetic and ferrimagnetic. Of these, ferro and ferri magnetic materials assume great commercial importance due to their unique properties like appropriate magnetic characteristics, high resistivity and low eddy current losses. The emergence of nanoscience and nanotechnology during the last decade had its impact in the field of magnetism and magnetic materials too. Now, it is common knowledge that materials synthesized in the nanoregime exhibit novel and superlative properties with respect to their coarser sized counterparts in the micron regime. These studies reveal that dielectric properties can be varied appreciably by high-energy ball milling in nanosized zinc ferrites produced by coprecipitation method. A semi conducting behaviour was observed in these materials with the Oxygen vacancies acting as the main charge carrier for conduction, which was produced at the time of coprecipitation and milling. Thus through this study, it was possible to successfully investigate the finite size effects on the structural, electrical and magnetic properties of normal spinels in the ultra fine regime
Raghavan, Lisha; Prof. (Dr.) M. R. Anantharaman(Cochin University of Science and Technology, August 9, 2015)
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Abstract:
Magnetism and magnetic materials have been playing a lead role in the day to day life of human beings. The human kind owes its gratitude to the ‘lodestone’ meaning ‘leading stone’ which lead to the discovery of nations and the onset of modern civilizations. If it was William Gilbert, who first stated that ‘earth was a giant magnet’, then it was the turn of Faraday who correlated electricity and magnetism. Magnetic materials find innumerable applications in the form of inductors, read and write heads, motors, storage devices, magnetic resonance imaging and fusion reactors. Now the industry of magnetic materials has almost surpassed the semiconductor industry and this speaks volumes about its importance. Extensive research is being carried out by scientists and engineers to remove obsolescence and invent new devices. Though magnetism can be categorized based on the response of an applied magnetic field in to diamagnetic, paramagnetic, ferromagnetic, ferrimagnetic and antiferromagnetic; it is ferrimagnetic, ferromagnetic and antiferromagnetic materials which have potential applications. The present thesis focusses on these materials, their composite structures and different ways and means to modify their properties for useful applications.