Matlrew, George; Dr.Anantharaman, M R(Cochin University of Science & Technology, February , 2004)
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Abstract:
Magnetism and magnetic materials have been an ever-attractive
subject area for engineers and scientists alike because of its versatility in
finding applications in useful devices. They find applications in a host of
devices ranging from rudimentary devices like loud speakers to sophisticated
gadgets like waveguides and Magnetic Random Access Memories (MRAM).The one and only material in the realm of magnetism that has been at the
centre stage of applications is ferrites and in that spinel ferrites received the
lions share as far as practical applications are concerned.It has been the endeavour of scientists and engineers to remove
obsolescence and improve upon the existing so as to save energy and
integrate in to various other systems. This has been the hallmark of material
scientists and this has led to new materials and new technologies.In the field of ferrites too there has been considerable interest to
devise new materials based on iron oxides and other compounds. This means
synthesising ultra fine particles and tuning its properties to device new
materials. There are various preparation techniques ranging from top- down
to bottom-up approaches. This includes synthesising at molecular level, self
assembling,gas based condensation. Iow temperature eo-precipitation, solgel
process and high energy ball milling. Among these methods sol-gel
process allows good control of the properties of ceramic materials. The
advantage of this method includes processing at low temperature. mixing at
the molecular level and fabrication of novel materials for various devices.Composites are materials. which combine the good qualities of one
or more components. They can be prepared in situ or by mechanical means
by the incorporation of fine particles in appropriate matrixes. The size of the
magnetic powders as well as the nature of matrix affect the processability
and other physical properties of the final product. These plastic/rubber
magnets can in turn be useful for various applications in different devices.
In applications involving ferrites at high frequencies, it is essential that the
material possesses an appropriate dielectric permittivity and suitable
magnetic permeability. This can be achieved by synthesizing rubber ferrite
composites (RFC's). RFCs are very useful materials for microwave
absorptions. Hence the synthesis of ferrites in the nanoregirne.investigations on their size effects on the structural, magnetic, and electrical
properties and the incorporation of these ferrites into polymer matrixes
assume significance.In the present study, nano particles of NiFe204, Li(!5Fe2S04 and
Col-e-O, are prepared by sol gel method. By appropriate heat treatments,
particles of different grain sizes are obtained. The structural, magnetic and
electrical measurements are evaluated as a function of grain size and
temperature. NiFel04 prepared in the ultrafine regime are then incorporated
in nitrile rubber matrix. The incorporation was carried out according to a
specific recipe and for various loadings of magnetic fillers. The cure
characteristics, magnetic properties, electrical properties and mechanical
properties of these elastomer blends are carried out. The electrical
permittivity of all the rubber samples in the X - band are also conducted.
Description:
Department of Physics,
Cochin University of Science & Technology
Sindhu, S; Dr.Anantharaman, M R(Cochin University of Science and Technology, April , 2001)
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Abstract:
The objectives of the proposed work are preparation of ceramic nickel zinc ferrite belonging to the series Ni1-XZnXFe2O4 with x varying from 0 to 1in steps of 0.2, structrural, magnetic and electrical characterization of Ni1-XZnXFe2O4, preparation and evaluation of Cure characteristics of Rubber Ferrite Composites (RFCs), magnetic characterization of RFCs using vibrating sample magnetometer (VSM), electrical characterization of RFCs and estimation of magnetostriction constant form HL parameters. The study deals with the structural and magnetic properties of ceramic fillers, variation of coercivity with composition and the variation of magnetization for different filler loadings are compared and correlated. The dielectric properties of ceramic Ni1-XZnXFe2O4 and rubber ferrite composites containing Ni1-XZnXFe2O4 were evaluated and the ac electrical conductivity (ac) of ceramic as well as composite samples can be calculated by using a simple relationship of the form ac = 2f tan 0r, with the data available from dielectric measurements. The results suggest that the ac electrical conductivity is directly proportional to the frequency
Malini, K A; Dr.Anantharaman, M R(Cochin University of Science and Technology, May 30, 2001)
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Abstract:
This thesis mainly deals with the preparation and studies on magnetic composites based on spinel ferrites prepared both chemically and mechanically. Rubber ferrite composites (RFC) are chosen because of their mouldability and flexibility and the ease with which the dielectric and magnetic properties can be manipulated to make them as useful devices. Natural rubber is chosen as the
Matrix because of its local availability and possible value addition. Moreover, NR represents a typical unsaturated nonpolar matrix. The work can be thought of as two parts. Part l concentrates on the preparation and characterization of nanocomposites based on y-Fe203. Part 2 deals with the preparation and characterization of RFCs containing Nickel zinc ferrit In the present study magnetic nanocomposites have been prepared by ionexchange method and the preparation conditions have been optimized. The insitu incorporation of the magnetic component is carried out chemically. This method is selected as it is the easiest and simplest method for preparation of nanocomposite. Nanocomposite samples thus prepared were studied using VSM, Mossbauer spectroscopy, Iron content estimation, and ESR spectroscopy. For the preparation of RFCs, the filler material namely nickel zinc ferrite having the general formula Ni)_xZnxFez04, where x varies from 0 to 1 in steps of 0.2 have been prepared by the conventional ceramic techniques. The system of Nil_xZn"Fe204 is chosen because of their excellent high frequency characteristics. After characterization they are incorporated into the polymer matrix of natural rubber by mechanical method. The incorporation is done according to a specific recipe and for various Loadings of magnetic fillers and also for all compositions. The cure characteristics, magnetic properties and dielectric properties of these composites are evaluated. The ac electrical conductivity of both ceramic nickel zinc ferrites and rubber ferrite composites are also calculated using a simple relation. The results are correlated.
Description:
Physics Department,
Cochin UniversIty of Science & Technology