Yoosaf, K; Dr. George Thomas, K(Chemical Sciences and Technology Division,CSIR, January , 2008)
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Abstract:
Most of the procedures reported for the synthesis of metal
nanoparticles involve the use of strong reducing agents or elevated
temperatures. This limits the possibility of developing metal nanoparticle
based sensors for the in situ detection of analytes. One of the objectives of
the present investigations is to (i) develop newer methodologies for the
synthesis of metal nanoparticles in aqueous medium at ambient conditions
and (ii) their use in the detection of metal cations by taking advantage of
the unique coordination ability. Ideally, biocompatible molecules which
possess both the reducing and stabilizing groups are desirable for such
applications. Formation of stable supramolecular assembly, by bringing metal nanoparticles close to each other, results in plasmon coupling and
this strategy can be effectively utilized for the development of metal
nanoparticle based sensors.Another objective of the present study is to understand the
supramolecular organization of molecules on surfaces. Various
noncovalent interactions between the molecules and with surface play a
decisive role in their organizations. An in-depth understanding of these
interactions is essential for device fabrications. Recent photophysical
studies have revealed that phenyleneethynylene based molecular systems
are ideal for device application. The second objective of the thesis focuses
on understanding the (i) organization of phenyleneethynylenes on highly
oriented pyrolytic graphite (HOPG) surface with atomic level precision and
(ii) weak intermolecular interactions which drive their organization.
Jose P, Kalloopparambil; Dr.Girish Kumar, K(Cochin University of Science & Technology, November , 2006)
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Abstract:
Polymer supports are efficient reagents,substrates and catalysts and they are extensively used for carrying out reactions at controlled rates.Tailor-made polymer supports are highly versatile which have opened an excellent area of research.Now polymer supported chemistry is being exploited at an amazing rate and it seems to join the routine world of organic synthesis.Polymer supported ligands are found to be efficient complexing agents whose high selectivity enables the analysis and removal of heavy metal ions which are toxic to all the living organisms of land and sea.polymer supported membranes function as ion selective potentiometric sensors which allow the exchange of specific ions among other ions of the same charge.In this investigation three series of polymeric schiff bases and three series of metal complexes have been prepared.An attempt is done to develop optimum conditions for the removal of heavy metal ions using polymeric schiff bases.A novel copper sensor electrode have also been prepared from polymer supported metal complex.
Description:
Department of Applied Chemistry,
Cochin University of Science and Technology
Binu, Varghese; Dr.Prathapachandra Kurup,M R(Cochin University of Science & Technology, February , 2009)
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Abstract:
The thesis is an introduction to our attempts to evaluate
the coordination behaviour of a few compounds of our interest.
Semicarbazones and their metal complexes have been an active area of
research during the past years because of the beneficial biological activities
of these substances. Tridentate NNO semicarbazone systems formed from
heterocyclic and aromatic carbonyl compounds and their transition metal
complexes are well-authenticated compounds in this field and their
synthesis and characterization are well desirable. Hence, we decided to
develop a research program aimed at the synthesis and characterization of
novel semicarbazones derived from 2-benzoylpyridine and 2-acetylpyridine
and their transition metal complexes. In addition to various physicochemical
methods of analysis, single crystal X—Ray diffraction studies were
also used for the characterization of the complexes.
Description:
Department of Applied Chemistry,
Cochin University of Science and Technology
Laly, K; Dr.Prathapachandra Kurup,M R(Cochin University of Science and Technology, July , 2011)
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Abstract:
In the present work,the chelating behaviour of thiosemicarbazones of a heterocyclic diketone, 2,6-diacetylpyridine is studied,with the aim of investigating the influence coordination exerts on their conformation and /or configuration, in connection with the nature of the metal and of the counter ion.The various possibilities like unsubstitution,ring incorporation at terminal nitrogen and condensation of one of the ketone group alone have been tried for ligand selection.Mainly first row transition metals like manganese,iron,nickel,copper,zinc and cadmium are studied.Metals like cobalt also were studied but could not result in fruitful isolation of the compound due to solubility problems.Different spectroscopic and characterization techniques have been utilized to reveal the nature of the metal and the ligands in coordinated metal complex.
Description:
Department of Applied Chemistry,Cochin University of Science and Technology