Girish Kumar,K; Saji John,Konnully(Department of Applied Chemistry, August 1, 2006)
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Abstract:
Salicylaldehyde Schiff base of amino-methylated
polystyrene has been developed as a novel reagent for the removal
of Fe(III) from solutions. The selectivity of the metal
ion uptake over a wide range of different concentrations of
metal ion, effect of pH, ligand concentration and the influence
of other foreign ions were studied. A very good selectivity
was achieved for the removal of the ion. It was found
that 0.01 g of the ligand was sufficient to achieve about 96%
removal of the metal ion in terms of concentration (ppm)
from a 30 ppm solution in acidic pH.
Seena, E B; Prathapachandra Kurup, M R(Elsevier, 2007)
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Abstract:
Three copper(II) complexes of salicylaldehyde N(4)-phenyl thiosemicarbazone (H2L1) and two copper(II) complexes of N(4)-cyclohexyl thiosemicarbazone (H2L2) have been synthesized and characterized by different physicochemical techniques like magnetic studies and electronic, infrared and EPR spectral studies. The complexes View the MathML source and [(CuL2)2] (4) having dimeric structure. The thiosemicarbazones bind to the metal as dianionic ONS donor ligand in all the complexes, except in the complex [Cu(HL1)2] · H2O (2). In complex 2, the ligand moieties are coordinated as monoanionic (HL−) ones. Two of the complexes [CuL1dmbipy] · H2O (3) and [CuL2dmbipy] (5) have been found to possess the stoichiometry [CuLB], where B = 4,4′-dimethyl-2,2′-bipyridine (dmbipy). The coordination geometry around copper(II) in 5 is trigonal bipyramidal distorted square based pyramidal (TBDSBP), as obtained by X-ray diffraction studies.
Prathapachandra Kurup, M R; Seena, E B; Leji, Latheef(Elsevier, November 1, 2008)
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Abstract:
A novel binuclear Ni(II) complex of salicylaldehyde 3-azacyclothiosemicarbazone (H2L) has been synthesized
and characterized by elemental analysis, IR and UV–Vis spectroscopy. The single crystal X-ray structure
of the complex shows that bridging occurs through thiolato sulfur and phenolic oxygen atoms.
Nickel centers in the complex have square planar and octahedral geometries